i'm a gas engineer rather than a plumber but i do see a whole host of different systems when i'm in peoples houses.
does he have a shower running of his combi in the exisiting bathroom? i was under the impression that combi's can provide quite a powerful shower as they are, much more so than an electric shower, esp if he has a powerful boiler of 30kw or more.
another option may be to convert his existing system to include a water storeage cylinder in the loft to give him greater flow and pressure, the combi could then heat the cylinder and perhaps he could have an additional high pressure pump from the cylinder to the shower.. this would be cheaper than an extra boiler and cylinder and power shower pump.
or he could have a system boiler put in and an unvented hot water cylinder to give mains pressure water which would give him a great flow of hot water to every tap and shower, again cheaper than 2 seperate systems and boilers.
my advice would be to pop in to your nearest plumbers merchants and ask the counter staff there for their advice, note down what make, model and power output of boiler you have to make it easier for them.
also ring a couple of plumbers and ask them for a free quote and the different options.