Not with 100% accuracy. Gene technology at the moment can classify someone into one of three eye-colour groups - light (blue and grey), dark (black and brown), or hazel. The accuracy is around 97% but sometimes other factors are involved which seriously hinder accurate analysis.
Not quite Katoninelive. You could only say for certain that the eyes would be blue, grey or shades in between.
You could exclude black, brown, hazel and their variants with a reasonable amount of certainty.
However, there are circumstances in which this type of DNA analysis is inconclusive so for forensic purposes, you still couldn't be 100% positive as to the eye colour or shade. This is the reason why eye colour is of little value in forensic science.