I am assuming you are using a recent version of Windows on your PC? I have not used XP, so not sure if this is the same for that, but formerly, if your picture is saved in "My Pictures" you just highlight it with your mouse, then right click on the mouse. You will get a menu that includes "Send To.." point to this and you should see a list of destinations, including your CD burner. Also, whatever CD burning software you are using should have instructions on how to select files on your PC for transferring to a CD.