Smell: Close your mouth and pinch your nose and you will experience the difficulty of inhaling in the near vacuum of space.
Sound: is the mechanical energy of air or another medium, therefore no sound except for the stray meteoroid striking your eardrum.
Temperature: The temperature of space at the radius of the Earth is cold but actually well above freezing at seven degrees centigrade, perhaps a bit cooler than the average temperature over the surface of the Earth. You would want to be spinning to balance the extremes of sunlight and shade but your shaded parts would not freeze immediately because heat transfer would only be due to radiation since there is nothing (no air) to transfer your heat to.
Pressure, on the other hand, would soon become a problem, especially if you were to try to hold your breath your lungs and eardrums would burst,
POP in stereo.
You might have a minute to enjoy all this before perminent damage occured due to lack of oxygen.
space exposure